Which of the following reduction reaction CANNOT be carried out with coke ?

Question:
Which of the following reduction reaction CANNOT be carried out with coke ?

$\mathrm{Al}_{2} \mathrm{O}_{3} \rightarrow \mathrm{Al}$
$\mathrm{ZnO} \rightarrow \mathrm{Zn}$
$\mathrm{Fe}_{2} \mathrm{O}_{3} \rightarrow \mathrm{Fe}$
$\mathrm{Cu}_{2} \mathrm{O} \rightarrow \mathrm{Cu}$

Correct Option: 1

Solution:

Reduction of $\mathrm{Al}_{2} \mathrm{O}_{3} \rightarrow \mathrm{Al}$ is carried out by electrolytic reduction of its fused salts.

$\mathrm{ZnO}, \mathrm{Fe}_{2} \mathrm{O}_{3} \& \mathrm{Cu}_{2} \mathrm{O}$ can be reduce by carbon.

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