Question:
The decomposition of hydrocarbon follows the equation
k = (4.5 × 1011 s−1) e−28000 K/T
Calculate Ea.
Solution:
The given equation is
k = (4.5 × 1011 s−1) e−28000 K/T (i)
Arrhenius equation is given by,
$k=\mathrm{Ae}^{-E_{\alpha} / \mathrm{R} T}$
From equation (i) and (ii), we obtain
$\frac{E_{a}}{\mathrm{R} T}=\frac{28000 \mathrm{~K}}{T}$
$\Rightarrow E_{a}=\mathrm{R} \times 28000 \mathrm{~K}$
= 8.314 J K−1 mol−1 × 28000 K
= 232792 J mol−1
= 232.792 kJ mol−1