On the basis of thermochemical equations (a),

Question:

On the basis of thermochemical equations (a), (b) and (c), find out which of the

algebraic relationships given in options (i) to (iv) is correct.

(a) C (graphite) + O2 (g) → CO2 (g) ; ∆rH = x kJ mol–1

(b) C (graphite) +12 O2 (g) → CO (g) ; ∆rH = y kJ mol–1

(c) CO (g) +12 O2 (g) → CO2 (g) ; ∆rH = z kJ mol–1

(i) z = x + y

(ii) x = y – z

(iii) x = y + z

(iv) y = 2z – x

Solution:

Option (iii) x = y + z  is the answer.

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