Let the vectors

It is given that $|\vec{a}|=3$ and $|\vec{b}|=\frac{\sqrt{2}}{3}$.

We know that $\vec{a} \times \vec{b}=|\vec{a}||\vec{b}| \sin \theta \hat{n}$, where $\hat{n}$ is a unit vector perpendicular to both $\vec{a}$ and $\vec{b}$ and $\theta$ is the angle between $\vec{a}$ and $\vec{b}$.

Now, $\vec{a} \times \vec{b}$ is a unit vector if $|\vec{a} \times \vec{b}|=1$.

$|\vec{a} \times \vec{b}|=1$

$\Rightarrow|\vec{a}||\vec{b}| \sin \theta \hat{n} \mid=1$

$\Rightarrow|\vec{a}||\vec{b}||\sin \theta|=1$

$\Rightarrow 3 \times \frac{\sqrt{2}}{3} \times \sin \theta=1$

$\Rightarrow \sin \theta=\frac{1}{\sqrt{2}}$

$\Rightarrow \theta=\frac{\pi}{4}$

Hence, $\vec{a} \times \vec{b}$ is a unit vector if the angle between $\vec{a}$ and $\vec{b}$ is $\frac{\pi}{4}$.

The correct answer is B.