Question:
How much electricity is required in coulomb for the oxidation of
(i) 1 mol of H2O to O2.
(ii) 1 mol of FeO to Fe2O3.
Solution:
(i) According to the question,
$\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{H}_{2}+\frac{1}{2} \mathrm{O}_{2}$
Now, we can write:
$\mathrm{O}^{2-} \longrightarrow \frac{1}{2} \mathrm{O}_{2}+2 \mathrm{e}^{-}$
Electricity required for the oxidation of 1 mol of H2O to O2 = 2 F
= 2 × 96487 C
= 192974 C
(ii) According to the question,
$\mathrm{Fe}^{2+} \longrightarrow \mathrm{Fe}^{3+}+\mathrm{e}^{-1}$
Electricity required for the oxidation of 1 mol of FeO to Fe2O3 = 1 F
= 96487 C