How many electrons in an atom may have the following quantum numbers?

Question.

How many electrons in an atom may have the following quantum numbers?

(a) $n=4$

$m_{x}=-\frac{1}{2}$

(b) $n=3, I=0$



Solution:

(a) Total number of electrons in an atom for a value of $n=2 n^{2}$

$\therefore$ For $n=4$,

Total number of electrons $=2(4)^{2}=32$

The given element has a fully filled orbital as

$1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{10}$

Hence, all the electrons are paired.

$\therefore$ Number of electrons (having $n=4$ and $\left.m_{x}=-\frac{1}{2} \quad\right)=16$

(b) $n=3, I=0$ indicates that the electrons are present in the $3 s$ orbital. Therefore,

the number of electrons having $n=3$ and $I=0$ is 2 .

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