Given below are two statements:

Question:

Given below are two statements:

Statement $\mathrm{I}$ : The $\mathrm{E}^{\circ}$ value of $\mathrm{Ce}^{4+} / \mathrm{Ce}^{3+}$ is $+1.74 \mathrm{~V}$

Statement II : Ce is more stable in $\mathrm{Ce}^{4+}$ state than $\mathrm{Ce}^{3+}$ state.

In the light of the above statements, choose the most appropriate answer from the options given below:

  1. Both statement I and statement II are correct

  2.  Statement $\mathrm{I}$ is incorrect but statement $\mathrm{II}$ is correct

  3. Both statement I and statement II are incorrect

  4.  Statement I is correct but statement II is incorrect.


Correct Option: , 4

Solution:

The $\mathrm{E}^{\circ}$ value for $\mathrm{Ce}^{4+} / \mathrm{Ce}^{3+}$ is $+1.74 \mathrm{~V}$ because the most stable oxidation state of lanthanide series elements is $+3$. It means $\mathrm{Ce}^{3+}$ is more stable than $\mathrm{Ce}^{4+} .$

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