Given below are two statements:

Question:

Given below are two statements:

Statement $\mathrm{I}: \mathrm{CeO}_{2}$ can be used for oxidation of aldehydes and ketones.

Statement II : Aqueous solution of $\mathrm{EuSO}_{4}$ is a strong reducing agent.

In the light of the above statements, choose the correct answer from the options given below:

  1. Statement I is false but statement II is true 

  2. Statment I is true but statement II is false 

  3. Both statement I and statement II are true 

  4. Both statement I and statement II are false


Correct Option: , 3

Solution:

The $+3$ oxidation state of lanthanide is most stable and therefore lanthanide in $+4$ oxidation state has strong tendence to gain $\mathrm{e}^{-}$and converted into $+3$ and therefore act as strong oxidizing agent.

eg $\mathrm{Ce}^{+4}$

And there fore $\mathrm{CeO}_{2}$ is used to oxidized alcohol aldehyde and ketones.

Lanthanide in $+2$ oxidation state has strong tendency to loss $\mathrm{e}^{-}$and converted into $+3$ oxidation state therefore act as strong reducing agent.

$\therefore \mathrm{EuSO}_{4}$ act as strong reducing agent.

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