Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R :

Question:

Given below are two statement : one is labelled as Assertion A and the other is labelled as Reason R :

Assertion A : Size of Bk3+ ion is less than Np3+ ion.

Reason R : The above is a consequence of the lanthanoid contraction. In the light of the above statements, choose the correct answer from the options given below

  1. (1) A is false but R is true

  2. (2) Both A and R are true but R is not the correct explanation of A

  3. (3) Both A and R are true and R is the correct explanation of A

  4. (4) A is true but R is falseĀ 


Correct Option: 4,

Solution:

Size of ${ }_{97} \mathrm{Bk}^{3+}$ ion is less than that of ${ }_{93} \mathrm{~Np}^{3+}$ due to actinoid contraction.

As we know that in a period from left to right ionic radius decreases and in actinide series it is due to actinoid contraction.

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