Calcium carbonate reacts with aqueous

Question:

Calcium carbonate reacts with aqueous HCl to give CaCl2 and CO2 according

to the reaction given below:

CaCO3 (s) + 2HCl (aq) → CaCl2(aq) + CO2(g) + H2O(l)

What mass of CaCl2 will be formed when 250 mL of 0.76 M HCl reacts with

1000 g of CaCO3? Name the limiting reagent. Calculate the number of moles

of CaCl2 formed in the reaction.

Solution:

No: of moles of HCl taken = MV/1000 = 0.76*250/1000 = 0.19

No: of moles of CaCO3 = Mass/Molar mass = 1000/100 = 10

1. When CaCO3 is completely consumed

1 mol of CaCO3 = 1 mol CaCl2

10 mol CaCO3 = 10mol CaCl2

2. When HCl is completely consumed.

2 mol HCl = 1 mol CaCl2

0.19mol HCl = ½  × 0.19mol CaCl2 = 0.095 mol CaCl2

HCl will be the limiting reagent and the number of moles of CaCl2 formed will be 0.095mol

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