A reaction is first order in A and second order in B.

Question:

A reaction is first order in A and second order in B.

(i) Write the differential rate equation.

(ii) How is the rate affected on increasing the concentration of B three times?

(iii) How is the rate affected when the concentrations of both A and B are doubled?

Solution:

(i) The differential rate equation will be

$-\frac{d[\mathrm{R}]}{d t}=k[\mathrm{~A}][\mathrm{B}]^{2}$

(ii) If the concentration of B is increased three times, then

$-\frac{d[\mathrm{R}]}{d t}=k[\mathrm{~A}][3 \mathrm{~B}]^{2}$

$=9 \cdot k[\mathrm{~A}][\mathrm{B}]^{2}$

Therefore, the rate of reaction will increase 9 times.

 

(iii) When the concentrations of both A and B are doubled,

$-\frac{d[\mathrm{R}]}{d t}=k[\mathrm{~A}][\mathrm{B}]^{2}$

$=k[2 \mathrm{~A}][2 \mathrm{~B}]^{2}$

$=8 \cdot k[\mathrm{~A}][\mathrm{B}]^{2}$

Therefore, the rate of reaction will increase 8 times.

 

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